Natural Glass


Natural Glass
1.  Obsidian
Obsidian is a naturally occurring volcanic glass formed as an extrusive rock. It is produced when felsic lava extruded from a volcano cools rapidly without crystal growth. Obsidian is commonly found within the margins of rhyolitic lava flows known as obsidian flows, where the chemical composition (high silica content) induces a high viscosity and polymerization degree of the lava. The inhibition of atomic diffusion through this highly viscous and polymerized lava explains the lack of crystal growth. Because of this lack of crystal structure, obsidian blade edges can reach almost molecular thinness, leading to its ancient use as projectile points and blades, and its modern use as surgical scalpel blades.

Origin and properties

Pliny's Natural History features volcanic glass called "Obsidianus", so named from its resemblance to a stone found in Ethiopia by one Obsius.
Obsidian is mineral-like, but not a true mineral because as a glass it is not crystalline; in addition, its composition is too complex to comprise a single mineral. It is sometimes classified as a mineraloid. Though obsidian is dark in color similar to mafic rocks such as basalt, obsidian's composition is extremely felsic. Obsidian consists mainly of SiO2 (silicon dioxide), usually 70% or more. Crystalline rocks with obsidian's composition include granite and rhyolite. Because obsidian is metastable at the Earth's surface (over time the glass becomes fine-grained mineral crystals), no obsidian has been found that is older than Cretaceous age. This breakdown of obsidian is accelerated by the presence of water. Obsidian has low water content when fresh, typically less than 1% water by weight, but becomes progressively hydrated when exposed to groundwater, forming perlite. Tektites were once thought by many to be obsidian produced by lunar volcanic eruptions, though few scientists now adhere to this hypothesis.
Pure obsidian is usually dark in appearance, though the color varies depending on the presence of impurities. Iron and magnesium typically give the obsidian a dark green to brown to black color. Very few samples are nearly colorless. In some stones, the inclusion of small, white, radially clustered crystals of cristobalite in the black glass produce a blotchy or snowflake pattern (snowflake obsidian). It may contain patterns of gas bubbles remaining from the lava flow, aligned along layers created as the molten rock was flowing before being cooled. These bubbles can produce interesting effects such as a golden sheen (sheen obsidian) or an iridescent, rainbow-like sheen

Occurrence

Obsidian can be found in locations which have experienced rhyolitic eruptions. It can be found in Argentina, Armenia, Canada, Chile, Greece, Guatemala, Iceland, Italy, Japan, Kenya, Mexico, New Zealand, Peru, Scotland and United States. Obsidian flows which may be hiked on are found within the calderas of Newberry Volcano and Medicine Lake Volcano in the Cascade Range of western North America, and at Inyo Craters east of the Sierra Nevada in California. Yellowstone National Park has a mountainside containing obsidian located between Mammoth Hot Springs and the Norris Geyser Basin, and deposits can be found in many other western U.S. states including Arizona, Colorado, New Mexico, Texas, Utah, Washington, Oregon and Idaho. Obsidian can also be found in the eastern U.S. state of Virginia.

Historical use

Obsidian was valued in Stone Age cultures because, like flint, it could be fractured to produce sharp blades or arrowheads. Like all glass and some other types of naturally occurring rocks, obsidian breaks with a characteristic conchoidal fracture. It was also polished to create early mirrors.
Modern archaeologists have developed a relative dating system, obsidian hydration dating, to calculate the age of obsidian artifacts.

Middle East

In Ubaid in the 5th millennium BC, blades were manufactured from obsidian mined in today's Turkey.

Americas

Lithic analysis can be instrumental in understanding prehispanic groups in Mesoamerica. A careful analysis of obsidian in a culture or place can be of considerable use to reconstruct commerce, production, distribution and thereby understand economic, social and political aspects of a civilization. This is the case in Yaxchilán, a Maya city where even warfare implications have been studied linked with obsidian use and its debris. Another example is the archeological recovery at coastal Chumash sites in California indicating considerable trade with the distant site of Casa Diablo, California in the Sierra Nevada Mountains.
Pre-Columbian Mesoamericans' use of obsidian was extensive and sophisticated; including carved and worked obsidian for tools and decorative objects. Mesoamericans also made a type of sword with obsidian blades mounted in a wooden body. Called a macuahuitl, the weapon was capable of inflicting terrible injuries, combining the sharp cutting edge of an obsidian blade with the ragged cut of a serrated weapon.
Native American people traded obsidian throughout the Americas. Each volcano and in some cases each volcanic eruption produces a distinguishable type of obsidian, making it possible for archaeologists to trace the origins of a particular artifact. Similar tracing techniques have allowed obsidian to be identified in Greece also as coming from Melos, Nisyros or Yiali, islands in the Aegean Sea. Obsidian cores and blades were traded great distances inland from the coast.
In Chile obsidian tools from Chaitén Volcano have been found as far away as in Chan-Chan 400 km north of the volcano and also in sites 400 km south of it.

Easter Island

Obsidian was also used on Rapa Nui (Easter Island) for edged tools such as Mataia and the pupils of the eyes of their Moai (statues).

Current use

Obsidian has been used for blades in surgery, as well-crafted obsidian blades have a cutting edge many times sharper than high-quality steel surgical scalpels, the cutting edge of the blade being only about 3 nanometres thick. Even the sharpest metal knife has a jagged, irregular blade when viewed under a strong enough microscope; when examined even under an electron microscope an obsidian blade is still smooth and even. One study found that obsidian incisions produced narrower scars, fewer inflammatory cells, and less granulation tissue in a group of rats.
Obsidian is also used for ornamental purposes and as a gemstone. It possesses the property of presenting a different appearance according to the manner in which it is cut: when cut in one direction it is jet black; in another it is glistening gray. "Apache tears" are small rounded obsidian nuggets embedded within a grayish-white perlite matrix.
Plinths for audio turntables have been made of obsidian since the 1970s; e.g. the greyish-black SH-10B3 plinth by Technics.

2.  Tektite

Tektites (from Greek τεκτός tektos, molten) are natural glass rocks up to a few centimeters in size, which most scientists argue were formed by the impact of large meteorites on Earth's surface. Tektites are typically black or olive-green, and their shape varies from rounded to irregular.Tektites are among the "driest" rocks, with an average water content of 0.005%. This is very unusual, as most if not all of the craters where tektites may have formed were underwater before impact. Also, partially melted zircons have been discovered inside a handful of tektites. This, along with the water content, suggests that the tektites were formed under phenomenal temperature and pressure not normally found on the surface of the Earth.

Origins

Terrestrial impact theory

The terrestrial-impact theory states that a meteorite impact melts material from the Earth's surface and catapults it up to several hundred kilometers away from the impact site, which means that it must have travelled through space (thus explaining the dryness). The molten material cools and solidifies to glass. According to this theory, a meteorite impact causes their formation, but the precursor material of tektites is primarily of terrestrial origin, as determined from isotopic measurements. Today, the terrestrial origin of tektites is widely accepted based on the results of many geochemical and isotopic studies, e.g. Faul, H.(1966) and Koeberl, C.(1990).
The impact theory relies on the observation that tektites cannot be found in most places on Earth's surface. They are only found in four strewnfields, three of which are associated with known impact craters. Only the largest and geologically youngest tektite deposit in Southeast Asia, called the Australasian strewnfield, has not been definitively linked to an impact site, probably because even very large impact structures are often not easy to detect. For example, since the Chesapeake Bay impact crater (today the largest known impact structure of the United States and associated with the North American tektite strewnfield) is covered by sediments, it was not detected until the early 1990s. Also, the bigger the strewnfield, the bigger the area to search for the crater. Since several new craters are identified every year, this is not really regarded as a problem by proponents of the tektite impact theory, except for the expected Australasian crater, a feature that would be less than a million years old and thus easily visible. This crater, if it exists at all, has not been located.
The ages of tektites from the four strewnfields have been determined using radiometric dating methods. The age of moldavites, a type of tektite found in Czech Republic, was determined to be 14 million years, which agrees well with the age determined for the Nördlinger Ries crater (a few hundred kilometers away in Germany) by radiometric dating of Suevite (an impact breccia found at the crater). Similar agreements exist between tektites from the North American strewnfield and the Chesapeake Bay impact crater and between tektites from the Ivory Coast strewnfield and the Lake Bosumtwi-Crater.
Below are some types of tektites, grouped according to the four known strewnfields, and their associated craters:
  • European strewnfield (Nördlinger Ries, Germany, age: 15 million years):
    • Moldavites (Czech Republic, green)
  • Australasian strewnfield (no associated crater identified; but see Wilkes Land crater):
    • Australites (Australia, dark, mostly black)
    • Indochinites (South East Asia, dark, mostly black)
    • Chinites (China, black)
  • North American strewnfield (Chesapeake Bay impact crater, USA, age: 34 million years):
    • Bediasites (USA, Texas, black)
    • Georgiaites (USA, Georgia, green)
  • Ivory Coast strewnfield (Lake Bosumtwi Crater, Ghana, age: 1 million years):
    • Ivorites (Ivory Coast, black)

Early nonterrestrial impact theories

Though the meteorite impact theory of tektite formation is widely accepted, minority theories propose alternate ideas of tektite formation.
Tektites contain no cosmogenic noble gases produced by cosmic rays, a factor that excludes long travel in space, necessary if tektites are not terrestrial. According to terrestrial-impact adherents, this makes a lunar origin unlikely, because it is hard to reconcile with finding cosmogenic noble gases in all lunar meteorites – a typical lunar meteorite taking about 1 million years to transfer from Moon to Earth. Furthermore, an origin from the Moon or other body cannot explain why many tektites are only found in confined areas unlike meteorites of lunar or other origin, which are found dispersed on the Earth's surface. Whether the Australasian and Ivory Coast tektites fit this thesis is debatable.
In particular, no tektite strewnfield exists in Antarctica, where the flow of glaciers would sweep extraterrestrial material away. Since the Australasian strewnfield expands with each new tektite discovered on the southern seafloor, this tektite field may yet be found to reach as far as Antarctica, but regularly undertaken meteorite recovery expeditions in areas that accumulate extraterrestrial material have found only meteorites and no tektites at all. If tektites from space fall in Antarctica, a large part of the recovered material should instead be tektites and an existing strewnfield should already have been discovered. Conversely, the Australasian and Ivory Coast strewnfields have expanded over the decades as new tektites are found in sea sediments; they now reach toward the southern continent. Thus, it may be premature for terrestrial-origin proponents to say that tektites will never be discovered on Antarctica.
According to researchers, measurements of high concentrations of the radionuclide 10Be in tektites from the relatively young Australasian strewnfield are an indication of terrestrial origin. 10Be is produced by cosmic rays in the atmosphere, where it is down-washed by rain and incorporated into young sediment layers. Because 10Be decays with a half-life of about 1.5 million years, its concentration in older sediments and other kinds of rocks appears successively lower. 10Be is found in meteorites and lunar rocks at a concentration lower than that of the young sediments because the cosmic rays interact with these rocks to produce much smaller quantities. Many regard these findings as the final breakthrough for the nonterrestrial impact theory, because they show that the precursor material is mainly terrestrial in origin (mixed with small traces of extraterrestrial material, perhaps that of the impactor). Scientists who claim tektite glasses are impact melts generally ignore their structure (petrography) and high quality. Instead, they base their claims on comparisons of tektite chemistries with the averages of certain sediments, and on certain rare-earth and isotopic values claimed not to exist in the Moon. Other researchers, however, have shown that tektite glasses are not really comparable to terrestrial sediments, which have a wide range of chemical variance – especially in the alkalis; and instead often exhibit igneous (volcanic) chemical trends. They also argue the physical impossibility of forming tektites by impact "jetting" or "compression rebound".
In 1961, officials at the U.S. Air Force's Cambridge Research Laboratories in Bedford, Massachusetts, were keenly interested in the chemical and physical characteristics of tektites. "Project 7698" was commissioned with W.H. Pinson, Jr. of the Massachusetts Institute of Technology as the principal investigator. The 7698 final report concluded that the strontium isotopic composition of tektites did not match those of terrestrial rocks and impactites. Pinson concluded the theory of formation by random fusion of terrestrial materials "whether by impact of meteorites, asteroids, comets or lightning" could not be supported.
It has been shown by researchers working on certain Apollo samples that a number of terrestrial-like rare-earth and isotopic values evidently do exist at depth in the Moon. Such samples have reached the surface in certain volcanic processes. Both terrestrial and lunar volcanism have produced iridium values comparable to that of the KT (Cretaceous/Tertiary) clay/microtektite layer. However, either terrestrial or lunar volcanism can not explain isotopic anomalism found in the KT boundary. In other words, chromium isotopic composition is homogeneous within the Earth-Moon system, so the chromium isotopic anomaly found in the KT boundary can be explained only if material from an impactor (asteroid or comet) were mixed in. Material of lunar origin, discovered to date, cannot explain the isotopic characteristics.
NASA scientist John A. O'Keefe published numerous papers between the 1950s and 1990s discussing these lunar rare-earth, isotopic and other chemistries, and how they relate to tektite glass.
Thus, some tektite researchers continue to strongly disagree with the popular terrestrial-impact theory; they suggest tektites are more likely volcanic ejecta from the Moon.
From the 1950s through the 1990s, NASA aerodynamicist Dean R. Chapman and others advanced the "lunar origin" theory of tektites. Chapman used complex orbital computer models and extensive wind tunnel tests to support the theory that the so-called Australasian tektites originated from the Rosse ejecta ray of the large crater Tycho on the Moon's nearside. Until the Rosse ray is sampled, a lunar origin for these tektites cannot be ruled out. During the 1980s and 1990s, researchers such as O’Keefe of NASA, astronomer and long-time tektite researcher Hal Povenmire, and petrologist Darryl Futrell claimed that the slow way in which tektite glass formed (called "fining"), and the volcanic features they claimed to have observed within some layered tektites, could not be explained by the terrestrial-impact theory. Unlike all terrestrial impactite glasses, tektites are nearly free of internal water, similar to lunar rocks. Also, Stokes' Law does not permit the formation of tektites during impact while the velocity needed to form certain "flanged" tektites is more compatible with a lunar origin rather than a terrestrial origin. O'Keefe suggested explosive, hydrogen-driven lunar volcanoes as the original source of tektites. Note: Since the unmanned U.S. Clementine lunar mission of the 1990s, vast areas of pyroclastic (volcanic) glasses have been identified, notably in the area of the Aristarchus plateau. There is also evidence of interstitial granitic material (akin to the acidic tektites in chemistry) in some lunar highland samples which bolsters the lunar-origin theory. Lunar Orbiter spacecraft images reveal fields of volcanic domes that may indicate deep-seated, high-silica eruptions on the Moon, possible sources of the tektites. (These domes are similar to the Mono Lake craters of California; ironically, Mono obsidians resemble some layered tektites).
A part of one of the rock samples collected on Apollo 12, lunar sample 12013, has a composition which is remarkably similar to some tektites. It is especially similar to high-magnesium javenites (part of the Australasian field). Sample 12013 is inhomogenous in that it is composed of two types of materials, light and dark. The light, acidic portion is composed of up to 71 percent silicon dioxide. The dark portion resembles KREEP rocks. The abundances of 20 of 23 elements tested from the acidic portion of the sample showed a striking similarity to high-magnesium tektites. The major elements matched well; the minor and trace elements did not. However, other lunar samples matched some microtektites very well.
Even with great similarity to a tektite, lunar sample 12013 is not generally accepted as a tektite. However, it is similar enough to some tektites that it cannot be ignored. Thus, mineralogist Brian Mason and petrologist W.G. Melson, geologists Edward Chao, Robert J. Foster, and Jack Green – along with astronomers Mark R. Chartrand, Franklyn Branley, J.E. van Zyl, Paolo Maffei and ceramic scientist David Pye – reject the terrestrial-origin theory and support a lunar origin.
Finally, according to O'Keefe and Povenmire, Apollo 14 lunar sample 14425 resembles some high-magnesium, low silica content microtektites. However, this claim was rejected in a study by scientist B.P. Glass. Regardless, O'Keefe said that "If 14425 was found in Antarctica instead of Fra Mauro (on the Moon), it would probably have been accepted as a tektite."
While the more visible tektite-origin "battle" may have quieted down since the Apollo era, it continues among some serious meteorite researchers and collectors who have studied the topic in depth and refuse to surrender their favorite theory.

Occurrence

The Moldau River (in Czech, Vltava) in the Czech Republic is now the only known locality for green, transparent tektite. The first tektites were found in 1787 in the Moldau River, hence their original name of "moldavites." Other color varieties of this natural glass have since been found in many different localities. Tektites are usually translucent and occur in a range of colors from green to brown. Their surfaces are usually uneven or rough, with a distinctive lumpy, jagged, or scarred texture. Tektites do not contain the crystallites found in obsidian. They may, however, have characteristic inclusions of round or torpedo-shaped bubbles or honeylike swirls. Tektites from Thailand have been carved as small, decorative objects worn in the belief that they give protection from evil.