Corundum
Corundum is a crystalline form of aluminium oxide (Al2O3) with traces of iron, titanium and chromium.It is a rock-forming mineral. It is one of the naturally clear transparent materials, but can have different colors when impurities are present. Transparent specimens are used as gems, called ruby if red, while all other colors are called sapphire.
The name "corundum" is derived from the Tamil word குருந்தம் "kuruntam" meaning "ruby", itself derived from the Sanskrit "kuruvinda".
Because of corundum's hardness (pure corundum is defined to have 9.0 Mohs), it can scratch almost every other mineral. It is commonly used as an abrasive, on everything from sandpaper to large machines used in machining metals, plastics, and wood. Some emery is a mix of corundum and other substances, and the mix is less abrasive, with an average hardness near 8.0.
In addition to its hardness, corundum is unusual for its density of 4.02 g/cm3, which is very high for a transparent mineral composed of the low atomic mass elements aluminium and oxygen.
Geology and occurrence
Corundum occurs as a mineral in mica schist, gneiss, and some marbles in metamorphic terranes. It also occurs in low silica igneous syenite and nepheline syenite intrusives. Other occurrences are as masses adjacent to ultramafic intrusives, associated with lamprophyre dikes and as large crystals in pegmatites.Because of its hardness and resistance to weathering, it commonly occurs as a detrital mineral in stream and beach sands.The largest documented single crystal of corundum measured about 65×40×40 cm.
Corundum for abrasives is mined in Zimbabwe, Russia, and India. Historically it was mined from deposits associated with dunites in North Carolina, USA and from a nepheline syenite in Craigmont, Ontario. Emery grade corundum is found on the Greek island of Naxos and near Peekskill, New York, USA. Abrasive corundum is synthetically manufactured from bauxite.
Synthetic corundum
In 1837, Gaudin made the first synthetic rubies by fusing alumina at a high temperature with a small amount of chromium as a pigment. In 1847, Ebelmen made white sapphires by fusing alumina in boric acid. In 1877 Frenic and Freil made crystal corundum from which small stones could be cut. Frimy and Auguste Verneuil manufactured artificial ruby by fusing BaF2 and Al2O3 with a little chromium at temperatures above 2,000 °C (3,632 °F). In 1903, Verneuil announced he could produce synthetic rubies on a commercial scale using this flame fusion process.
The Verneuil process allows the production of flawless single-crystal sapphires, rubies and other corundum gems of much larger size than normally found in nature. It is also possible to grow gem-quality synthetic corundum by flux-growth and hydrothermal synthesis. Because of the simplicity of the methods involved in corundum synthesis, large quantities of these crystals have become available on the market causing a significant reduction of price in recent years. Apart from ornamental uses, synthetic corundum is also used to produce mechanical parts (tubes, rods, bearings, and other machined parts), scratch-resistant optics, scratch-resistant watch crystals, instrument windows for satellites and spacecraft (because of its transparency from the UV to IR), and laser components.
Varieties
Ruby
The ruby is a pink to blood-red colored gemstone, a variety of the mineral corundum (aluminium oxide). The red color is caused mainly by the presence of the element chromium. Its name comes from ruber, Latin for red. Other varieties of gem-quality corundum are called sapphires. The ruby is considered one of the four precious stones, together with the sapphire, the emerald, and the diamond.
Prices of rubies are primarily determined by color. The brightest and most valuable "red" called pigeon blood-red, commands a huge premium over other rubies of similar quality. After color follows clarity: similar to diamonds, a clear stone will command a premium, but a ruby without any needle-like rutile inclusions may indicate that the stone has been treated. Cut and carat (weight) also determine the price.
Physical properties
Rubies have a hardness of 9.0 on the Mohs scale of mineral hardness. Among the natural gems only moissanite and diamond are harder, with diamond having a Mohs hardness of 10.0 and moissonite falling somewhere in between corundum (ruby) and diamond in hardness. Ruby is α-alumina (the most stable form of Al2O3) in which a small fraction of the aluminum3+ ions are replaced by chromium3+ ions. Each Cr3+ is surrounded octahedrally by six O2- ions. This crystallographic arrangement strongly affects each Cr3+, resulting in light absorption in the yellow-green region of the spectrum and thus in the red color of the gem. When yellow-green light is absorbed by Cr3+, it is re-emitted as red luminescence. This red emission adds to the red colour perceived by the subtraction of green and violet light from white light, and adds luster to the gem's appearance. When the optical arrangement is such that the emission is stimulated by 694-nanometer photons reflecting back and forth between two mirrors, the emission grows strongly in intensity. This effect was used by Theodore Maiman in 1960 to make the first successful laser, based on ruby.
All natural rubies have imperfections in them, including color impurities and inclusions of rutile needles known as "silk". Gemologists use these needle inclusions found in natural rubies to distinguish them from synthetics, simulants, or substitutes. Usually the rough stone is heated before cutting. Almost all rubies today are treated in some form, with heat treatment being the most common practice. However, rubies that are completely untreated but still of excellent quality command a large premium.
Some rubies show a 3-point or 6-point asterism or "star". These rubies are cut into cabochons to display the effect properly. Asterisms are best visible with a single-light source, and move across the stone as the light moves or the stone is rotated. Such effects occur when light is reflected off the "silk" (the structurally oriented rutile needle inclusions) in a certain way. This is one example where inclusions increase the value of a gemstone. Furthermore, rubies can show color changes — though this occurs very rarely — as well as chatoyancy or the "cat's eye" effect.
Natural occurrence
The Mogok Valley in Upper Myanmar (Burma) was for centuries the world's main source for rubies. That region has produced some of the finest rubies ever mined, but in recent years very few good rubies have been found there. The very best color in Myanmar rubies is sometimes described as "pigeon's blood." In central Myanmar, the area of Mong Hsu began producing rubies during the 1990s and rapidly became the world's main ruby mining area. The most recently found ruby deposit in Myanmar is in Namya (Namyazeik) located in the northern state of Kachin.
Rubies have historically been mined in Thailand, the Pailin and Samlout District of Cambodia, and in Afghanistan. Rubies have rarely been found in Sri Lanka, where pink sapphires are more common. After the Second World War ruby deposits were found in Tanzania, Madagascar, Vietnam, Nepal, Tajikistan, and Pakistan. A few rubies have been found in the U.S. states of Montana, North Carolina, and South Carolina. More recently, large ruby deposits have been found under the receding ice shelf of Greenland. In 2002 rubies were found in the Waseges River area of Kenya.
There are reports of a large deposit of rubies found in 2009 in Mozambique, in Nanhumbir in the Cabo Delgado district of Montepuez.
Spinel, another red gemstone, is sometimes found along with rubies in the same gem gravel or marble. Red spinel may be mistaken for ruby by those lacking experience with gems. However, the finest red spinels can have a value approaching that of the average ruby.
Factors affecting value
Diamonds are graded using criteria that have become known as the four Cs, namely color, cut, clarity and carat weight. Similarly natural rubies can be evaluated using the four Cs together with their size and geographic origin.
Color: In the evaluation of colored gemstones, color is the single most important factor. Color divides into three components; hue, saturation and tone. Hue refers to "color" as we normally use the term. Transparent gemstones occur in the following hues: red, orange, yellow, green, blue, violet, purple and pink are the spectral hues. The first six are known as spectral hues; the last two are modified spectral hues. Purple is a hue that falls halfway between red and blue. Pink is a paler shade of red. In nature there are rarely pure hues so when speaking of the hue of a gemstone we speak of primary and secondary and sometimes tertiary hues. In ruby the primary hue must be red. All other hues of the gem species corundum are called sapphire. Ruby may exhibit a range of secondary hues. Orange, purple, violet and pink are possible.
The finest ruby is best described as being a vivid medium-dark toned red. Secondary hues add an additional complication. Pink, orange, and purple are the normal secondary hues in ruby. Of the three, purple is preferred because, firstly, the purple reinforces the red making it appear richer.Secondly, purple occupies a position on the color wheel halfway between red and blue. In Burma where the term pigeon blood originated, rubies are set in pure gold. Pure gold is itself a highly saturated yellow. Set a purplish-red ruby in yellow and the yellow neutralizes its complement blue leaving the stone appearing to be pure red in the setting.
Treatments and enhancements
Improving the quality of gemstones by treating them is common practice. Some treatments are used in almost all cases and are therefore considered acceptable. During the late 1990s, a large supply of low-cost materials caused a sudden surge in supply of heat-treated rubies, leading to a downward pressure on ruby prices.
Improvements used include color alteration, improving transparency by dissolving rutile inclusions, healing of fractures (cracks) or even completely filling them.
The most common treatment is the application of heat. Most, if not all, rubies at the lower end of the market are heat treated on the rough stones to improve color, remove purple tinge, blue patches and silk. These heat treatments typically occur around temperatures of 1800 °C (3300 °F).Some rubies undergo a process of low tube heat, when the stone is heated over charcoal of a temperature of about 1300 °C (2400 °F) for 20 to 30 minutes. The silk is only partially broken as the color is improved.
A less acceptable treatment, which has gained notoriety in recent years, is lead glass filling. Filling the fractures inside the ruby with lead glass dramatically improves the transparency of the stone, making previously unsuitable rubies fit for applications in jewelry. The process is done in four steps:
- The rough stones are pre-polished to eradicate all surface impurities that may affect the process
- The rough is cleaned with hydrogen fluoride
- The first heating process during which no fillers are added. The heating process eradicates impurities inside the fractures. Although this can be done at temperatures up to 1400 °C (2500 °F) it most likely occurs at a temperature of around 900 °C (1600 °F) since the rutile silk is still intact
- The second heating process in an electrical oven with different chemical additives. Different solutions and mixes have shown to be successful, however mostly lead-containing glass-powder is used at present. The ruby is dipped into oils, then covered with powder, embedded on a tile and placed in the oven where it is heated at around 900 °C (1600 °F) for one hour in an oxidizing atmosphere. The orange colored powder transforms upon heating into a transparent to yellow-colored paste, which fills all fractures. After cooling the color of the paste is fully transparent and dramatically improves the overall transparency of the ruby.
If a color needs to be added, the glass powder can be "enhanced" with copper or other metal oxides as well as elements such as sodium, calcium, potassium etc.
The second heating process can be repeated three to four times, even applying different mixtures. When jewelry containing rubies is heated (for repairs) it should not be coated with boracic acid or any other substance, as this can etch the surface; it does not have to be "protected" like a diamond.
Synthetic and imitation rubies
In 1837 Gaudin made the first synthetic rubies by fusing potash alum at a high temperature with a little chromium as a pigment. In 1847 Ebelmen made white sapphire by fusing alumina in boric acid. In 1877 Frenic and Freil made crystal corundum from which small stones could be cut. Frimy and Auguste Verneuil manufactured artificial ruby by fusing BaF2 and Al2O3 with a little Chromium at red heat. In 1903 Verneuil announced he could produce synthetic rubies on a commercial scale using this flame fusion process. By 1910, Verneuil's laboratory had expanded into a 30 furnace production facility, with annual gemstone production having reached 1,000 kg (2,205 lb) in 1907.
Other processes in which synthetic rubies can be produced are through the Czochralski's Pulling process, flux process, and the hydrothermal process. Most synthetic rubies originate from flame fusion, due to the low costs involved. Synthetic rubies may have no imperfections visible to the naked eye but magnification may reveal curves, striae and gas bubbles. The fewer the number and the less obvious the imperfections, the more valuable the ruby is; unless there are no imperfections (i.e., a "perfect" ruby), in which case it will be suspected of being artificial. Dopants are added to some manufactured rubies so they can be identified as synthetic, but most need gemological testing to determine their origin.
Synthetic rubies have technological uses as well as gemological ones. Rods of synthetic ruby are used to make ruby lasers and masers. The first working laser was made by Theodore H. Maiman in 1960 at Hughes Research Laboratories in Malibu, California, beating several research teams including those of Charles H. Townes at Columbia University, Arthur Schawlow at Bell Labs, and Gould at a company called TRG (Technical Research Group). Maiman used a solid-state light-pumped synthetic ruby to produce red laser light at a wavelength of 694 nanometers (nm). Ruby lasers are still in use. Rubies can also be used in applications where high hardness is required such as material for scanning probe tips in a coordinate measuring machine. Synthetic ruby is also used extensively in the metrology field, serving as stylus material for contact measuring instruments such as a Coordinate Measuring Machine (CMM).
Imitation rubies are also marketed. Red spinels, red garnets, and colored glass have been falsely claimed to be rubies. Imitations go back to Roman times and already in the 17th century techniques were developed to color foil red—by burning scarlet wool in the bottom part of the furnace—which was then placed under the imitation stone.Trade terms such as balas ruby for red spinel and rubellite for red tourmaline can mislead unsuspecting buyers. Such terms are therefore discouraged from use by many gemological associations such as the Laboratory Manual Harmonisation Committee (LMHC).
Records
- The Smithsonian's National Museum of Natural History in Washington DC, has received one of the world's largest and finest ruby gemstones. The 23.1 carats (4.6 g) Burmese ruby, set in a platinum ring with diamonds, was donated by businessman and philanthropist Peter Buck in memory of his late wife Carmen Lúcia. This gemstone displays a richly saturated red color combined with an exceptional transparency. The finely proportioned cut provides vivid red reflections. The stone was mined from the Mogok region of Burma (now Myanmar) in the 1930s.
- In 2007 the London jeweler Garrard & Co featured on their website a heart-shaped 40.63-carat ruby.
Historical and cultural references
- An early recorded note of the transport and trading of rubies arises in the literature on the North Silk Road of China, wherein about 200 BC rubies were carried along this ancient trackway moving westward from China.
- Rubies have always been held in high esteem in Asian countries. They were used to ornament armor, scabbards, and harnesses of noblemen in India and China. Rubies were laid beneath the foundation of buildings to secure good fortune to the structure.
Sapphire
Sapphire (Greek: σάπφειρος; sappheiros, "blue stone") is a gemstone variety of the mineral corundum, an aluminium oxide (α-Al2O3), when it is a color other than red or dark pink, in which case the gem would instead be called a ruby, considered to be a different gemstone. Trace amounts of other elements such as iron, titanium, or chromium can give corundum blue, yellow, pink, purple, orange, or greenish color. Pink-orange sapphires are also called padparadscha. Pure chromium is the distinct impurity of rubies. However, a combination of e.g. chromium and titanium can give a sapphire of a color distinct from red.
Sapphires are commonly worn as jewellery. Sapphires can be found naturally, by searching through certain sediments or rock formations, or they can be manufactured for industrial or decorative purposes in large crystal boules. Because of the remarkable hardness of sapphires (and of aluminum oxide in general), sapphires are used in some non-ornamental applications, including infrared optical components, such as in scientific instruments; small, high-durability windows (also used in scientific instruments); wristwatch crystals; and very thin electronic wafers, which are used as the insulating substrates of very special-purpose solid-state electronics (most of which are integrated circuits).
Natural sapphires
The sapphire is one of the two or three gem-varieties of corundum, with another one being the red or deep pink ruby. Although blue is their most well-known color, sapphires are made up of any color of corundum except for red (red ones are called rubies). Sapphires may also be colorless, and they are also found in shades of gray and black.
The cost of natural sapphires varies depending on their color, clarity, size, cut, and overall quality - as well as their geographic origin, oddly enough. Significant sapphire deposits are found in Eastern Australia, Thailand, Sri Lanka, Madagascar, East Africa, and in North America in a few locations, such as at "Gem Mountain", and in or near the Missouri River in the region around Helena, Montana.Sapphire and rubies are often found together in the same area, but one gem is usually more abundant.
Blue sapphire
Color in gemstones breaks down into three components: hue, saturation, and tone. Hue is most commonly understood as the "color" of the gemstone. Saturation refers to the vividness or brightness or "colorfulness" of the hue, and tone is the lightness to darkness of the hue. Blue sapphire exists in various mixtures of its primary (blue) and secondary hues, various tonal levels (shades) and at various levels of saturation (brightness).
Blue sapphires are evaluated based upon the purity of their primary hue. Purple, violet, and green are the most common secondary hues found in blue sapphires. Violet and purple can contribute to the overall beauty of the color, while green is considered to be distinctly negative. Blue sapphires with up to 15% violet or purple are generally said to be of fine quality. Blue sapphires with any amount of green as a secondary hue are not considered to be fine quality. Gray is the normal saturation modifier or mask found in blue sapphires. Gray reduces the saturation or brightness of the hue and therefore has a distinctly negative effect.
The color of fine blue sapphires can be described as a vivid medium dark violet to purplish blue where the primary blue hue is at least 85% and the secondary hue no more than 15% without the least admixture of a green secondary hue or a gray mask.
The 423 carats (85 g) Logan sapphire in the National Museum of Natural History, in Washington, D.C., is one of the largest faceted gem-quality blue sapphires in existence.
Fancy color sapphire
Yellow and green sapphires are also commonly found. Pink sapphires deepen in color as the quantity of chromium increases. The deeper the pink color the higher their monetary value as long as the color is trending towards the red of rubies.
Sapphires also occur in shades of orange and brown, and colorless sapphires are sometimes used as diamond substitutes in jewelry. Padparadscha sapphires often draw higher prices than many of even the finest blue sapphires. Recently, more sapphires of this color have appeared on the market as a result of a new artificial treatment method that is called "lattice diffusion".
Padparadscha
Padparadscha is a pink-orange corundum, with a low to medium saturation and light tone, originally being mined in Sri Lanka, but also found in deposits in Vietnam and Africa; Padparadscha sapphires are very rare and highly valued. The name derives from the Sinhalese word for lotus blossom. Along with rubies, they are the only type of corundum to be given their own name instead of being called a particular colored sapphire. Padparadscha used to be a subvariety of ruby. The rarest of all padparadschas is the totally natural variety, with no sign of treatment.
Star sapphire
A star sapphire is a type of sapphire that exhibits a star-like phenomenon known as asterism. Star sapphires contain intersecting needle-like inclusions (often the mineral rutile, a mineral composed primarily of titanium dioxide) that cause the appearance of a six-rayed "star"-shaped pattern when viewed with a single overhead light source.
The Black Star of Queensland is believed to be the largest star sapphire that has ever been mined, and it weighs 733 carats. The Star of India (weighing 563.4 carats) is thought to be the second-largest star sapphire, and it is currently on display at the American Museum of Natural History in New York City. The 182-carat Star of Bombay, located in the National Museum of Natural History, in Washington, D.C., is an example of a blue star sapphire. The value of a star sapphire, however, depends not only on the weight of the stone but also the body color, visibility and intensity of the asterism.
Color change sapphire
A rare variety of sapphire, known as color change sapphire, exhibits different colors in different light. Color change sapphires are blue in outdoor light and purple under incandescent indoor light; they may also be pink in daylight to greenish under fluorescent light. Some stones shift color well and others only partially, in that some stones go from blue to bluish purple. While color change sapphires come from a variety of locations, the gem gravels of Tanzania is the main source.
Certain synthetic color-change sapphires are sold as “lab” or “synthetic” alexandrite, which is accurately called an alexandrite simulant (also called alexandrium) since the latter is actually a type of chrysoberyl—an entirely different substance whose pleochroism is different and much more pronounced than color-change corundum (sapphire).
Source of color
Red rubies are corundum which contain chromium impurities that absorb yellow-green light and result in deeper ruby red color with increasing content. Purple sapphires contain trace amounts of vanadium and come in a variety of shades. Corundum that contains ~0.01% of titanium is colorless. If trace amounts of iron are present, a very pale yellow to green color may be seen. If both titanium and iron impurities are present together, however, the result is a magnificent deep-blue color.
Unlike localized ("interatomic") absorption of light which causes color for chromium and vanadium impurities, blue color in sapphires comes from intervalence charge transfer, which is the transfer of an electron from one transition-metal ion to another via the conduction or valence band. The iron can take the form Fe2+ or Fe3+, while titanium generally takes the form Ti4+. If Fe2+ and Ti4+ ions are substituted for Al3+, localized areas of charge imbalance are created. An electron transfer from Fe2+ and Ti4+ can cause a change in the valence state of both. Because of the valence change there is a specific change in energy for the electron, and electromagnetic energy is absorbed. The wavelength of the energy absorbed corresponds to yellow light. When this light is subtracted from incident white light, the complementary color blue results. Sometimes when atomic spacing is different in different directions there is resulting blue-green dichroism.
Intervalence charge transfer is a process that produces a strong colored appearance at a low percentage of impurity. While at least 1% chromium must be present in corundum before the deep red ruby color is seen, sapphire blue is apparent with the presence of only 0.01% of titanium and iron.
Treatments
Sapphires may be treated by several methods to enhance and improve their clarity and color. It is common practice to heat natural sapphires to improve or enhance color. This is done by heating the sapphires in air to temperatures between 500 and 1800 °C for several hours, or by heating in a nitrogen-deficient atmosphere oven for seven days or more. Upon heating, the stone becomes a more blue in color but loses some of the rutile inclusions (silk). When high heat temperatures are used, the stone loses all of the silk and becomes clear under magnification. Evidence of sapphire and other gemstones being subjected to heating goes back to, at least, Roman times. Un-heated stones are quite rare and will often be sold accompanied by a certificate from an independent gemological laboratory attesting to "no evidence of heat treatment".
Diffusion treatments are somewhat more controversial as they are used to add elements to the sapphire for the purpose of improving colors. Typically beryllium is diffused into a sapphire with very high heat, just below the melting point of the sapphire. Initially (c. 2000) orange sapphires were created with this process, although now the process has been advanced and many colors of sapphire are often treated with beryllium. It is unethical to sell beryllium-treated sapphires without disclosure, and the price should be much lower than a natural gem or one that has been enhanced by heat alone.
Treating stones with surface diffusion is generally frowned upon because when stones chip or are repolished/refaceted the 'padparadscha' colored layer can be removed. (There are some diffusion treated stones in which the color goes much deeper than the surface, however.) The problem lies in the fact that treated padparadschas are at times very difficult to detect, and they are the reason that getting a certificate from a reputable gemological lab (e.g., Gubelin, SSEF, AGTA, etc.) is recommended before investing in them.
According to Federal Trade Commission guidelines, in the United States, disclosure is required of any mode of enhancement that has a significant effect on the gem's value.
Mining
Sapphires are mined from alluvial deposits or from primary underground workings. The mining locations include Myanmar, Madagascar, Sri Lanka, Australia, Thailand, India, Pakistan, Afghanistan, Tanzania, Kenya, and China. The Logan sapphire, the Star of India, and the Star of Bombay originate from Sri Lankan mines. Madagascar is the world leader in sapphire production (as of 2007) specifically its deposits in and around the city of Ilakaka. Prior to the opening of the Ilakaka mines, Australia was the largest producer of sapphires (such as in 1987). In 1991, a new source of sapphires was discovered in Andranondambo, southern Madagascar. That area has been exploited for its sapphires started in 1993, but it was practically abandoned just a few years later - because of the difficulties in recovering sapphires in their bedrock. This kind of sapphire has been sold as the "Kashmir sapphire" in international markets.
In North America, sapphires have been mined mostly from deposits around Helena, Montana. A few gem-grade sapphires and rubies have also been found in the area of Franklin, N.C.
In December 2008, the world's largest uncut sapphire was found in the Dodoma Region of Tanzania. At 99% purity and 26.69 pounds (12.11 kg) or 60,500 carats, its size and purity make it an extremely rare and valuable museum piece.Carter Malouf Dodoma Sapphire GIA Report.
Synthetic sapphire
In 1902, the French chemist Auguste Verneuil developed a process for producing synthetic sapphire crystals. In the Verneuil process, named for him, fine alumina powder is added to an oxyhydrogen flame, and this is directed downward against a mantle. The alumina in the flame is slowly deposited, creating a teardrop shaped "boule" of sapphire material. Chemical dopants can be added to create artificial versions of the ruby, and all the other natural colors of sapphire, and in addition, other colors never seen in geology. Artificial sapphire material is identical to natural sapphire, except it can be made without the flaws that are found in natural stones. The disadvantage of Verneuil process is that the grown crystals have high internal strains. Many methods of manufacturing sapphire today are variations of the Czochralski process, which was invented in 1916. In this process, a tiny sapphire seed crystal is dipped into a crucible made of the precious metal rhodium, containing molten alumina, and them slowly withdrawn upward at a rate of one to 100 mm per hour. The alumina crystallizes on the end, creating long carrot-shaped boules of large size, up to 400 mm in diameter and weighing almost 500 kg.
In 2003, the world's production of synthetic sapphire was 250 tons (1.25 × 109 carats), mostly by the United States and Russia. The availability of cheap synthetic sapphire unlocked many industrial uses for this unique material:
The first laser was made with a rod of synthetic ruby. Titanium-sapphire lasers are popular due to their relatively rare capacity to be tuned to various wavelengths in the red and near-infrared region of the electromagnetic spectrum. They can also be easily mode-locked. In these lasers, a synthetically-produced sapphire crystal with chromium or titanium impurities is irradiated with intense light from a special lamp, or another laser, to create stimulated emission.
One application of synthetic sapphire is sapphire glass. Here glass is a layman term which refers not to the amorphous state, but to the transparency. Sapphire is not only highly transparent to wavelengths of light between 170 nm and 5.3 μm (the human eye can discern wavelengths from about 380 nm to 750 nm), but it is also five times stronger than glass and ranks a 9 on the Mohs Scale, and much tougher than tempered glass although not as much as synthetic stabilized zirconium oxide (such as yttria-stabilized zirconia). Along with zirconia and aluminium oxynitride, synthetic sapphire is used for shatter resistant windows in armored vehicles and various military body armor suits, in association with composites. Sapphire "glass" (although being crystalline) is made from pure sapphire boules by slicing off and polishing thin wafers. Sapphire glass windows are used in high pressure chambers for spectroscopy, crystals in high quality watches, and windows in grocery store barcode scanners since the material's exceptional hardness and toughness makes it very resistant to scratching.
Synthetic sapphire is industrially produced from agglomerated aluminum oxide, sintered and fused in an inert atmosphere (hot isostatic pressing for example), yielding a transparent polycrystalline product, slightly porous, or with more traditional methods such as Verneuil, Czochralski, flux method, etc., yielding a single crystal sapphire material which is non-porous and should be relieved of its internal stress.
One type of xenon arc lamp (originally called the "Cermax" its first brand name), which is now known generically as the "ceramic body xenon lamp", uses sapphire crystal output windows that tolerate higher thermal loads - and thus higher output powers when compared with conventional Xe lamps with pure silica window.
Thin sapphire wafers are also used as an insulating substrate in high-power, high-frequency CMOS integrated circuits. This type of IC is called a silicon on sapphire or "SOS" chip. These are especially useful for high-power radio-frequency (RF) applications such as those found in cellular telephones, police car and fire truck radios, and satellite communication systems. "SOS" allows for the monolithic integration of both digital and analog circuitry all on one IC chip.
The reason for choosing wafers of artificial sapphire, rather than some of other substance, for these subtrates is that sapphire has a quite low conductivity for electricity, but a much-higher conductivity for heat. Thus, sapphire provides good electrical insulation, while at the same time doing a good job at helping to conduct away the significant heat that is generated in all operating integrated circuits. Thus, the choice of sapphire material for these substrates was not an arbitrary one, but rather, it is a choice that is made for serious electronics engineering reasons.
Wafers of single-crystal sapphire material are also used in the semiconductor industry as a non-conducting substrate for the growth of devices based on gallium nitride (GaN). The use of the sapphire material significantly reduces the cost, because this has about one-seventh the cost of germanium. Gallium nitride on sapphire is commonly used in blue light-emitting diodes (LEDs).
Historical and cultural references
· Some etymologists propose an old Sanskrit origin to the Semitic word "sappir": a dark colored precious stone called "Shanipriya" (शनिप्रिय), from "shani" (शनि) meaning "Saturn" and "priya" (प्रिय), precious, i.e. "precious to Saturn".
· According to Rebbenu Bachya, and in many English Bible translations, the word "Sapir" in the verse Exodus 28:18 means "sapphire" and was the stone on the Ephod representing the tribe of Issachar. However, it has been suggested that the English word "sapphire" stems from the Hebrew word "sapir" (ספיר) (via the Greek word "sapphiros"; σάπφειρος). Sapphires were actually not known as a distinct stone before the time of the Roman Empire. They were earlier considered to be forms of the mineral jacinth, rather than needing a word of their own. Prior to the time of the Roman Empire, "sapphiros" referred to any blue gem in general.
